Publications

Watson, L. A.; Leahy, D.; Evans, P. A.; Caulton, K. G.  Characterization and Evaluation of the Pre-Catalyst Components Employed in the Stereospecific Rhodium-Catalyzed Allylic Substitution Reaction.  Submitted for publication.

Watson, L. A.; Walstrom, A. N.; Pink, M.; Caulton, K. G.  Reactivity of the 14-Valence Electron, Spin Triplet [(tBu2PCH2SiMe2)2N]RuCl, (PNPtBu)RuCl. Submitted for publication.

Benatan, E., Dene, J., Eppley, H. J., Geselbracht, M. J., Jamieson, E. R., Johnson, A. R., Reisner, B. A., Stewart, J. L., Watson, L. and Williams, B. S. JCE VIPEr: An Inorganic Teaching and Learning Community. J. Chem. Ed., 2009, 86, 766.

Benatan, E., Eppley, H. J., Geselbracht, M. J., Johnson, A. R., Reisner, B. A., Stewart, J. L., Watson, L. and Williams, B. S. IONiC: A Cyber-Enabled Community of Practice for Improving Inorganic Chemical Education. J. Chem. Ed., 2009, 86, 123.

Gerber, L. C. H.; Watson, L. A.; Parkin, S.; Wang, W.; Foxman, B. M.; Ozerov, O. V. Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand. Organometallics, 2007, 26, 4866.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. Operationally Unsaturated Pincer/Rhenium Complexes form Metal Carbenes from Cycloalkenes and Metal Carbynes from Alkanes. J. Am. Chem. Soc., 2007, 129, 6003.

Basuli, F.; Bailey, B. C.; Watson, L. A.; Tomaszewski, J.; Huffman, J. C.; Mindiola, D. J. Four-Coordinate Titanium Alkylidene Complexes: Synthesis, Reactivity, and Kinetic Studies Involving the Terminal Neopentylidene Functionality. Organometallics, 2005, 24, 1886.

Çelenligil-Çetin, R.; Watson, L. A.; Guo, C.; Foxman, B.; Ozerov, O. Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center. Organometallics, 2005, 24, 186.

Watson, L. A.; Pink, M.; Caulton, K. G.  The Fate of Nitric Oxide in Its Reaction with the 14-valence-electron Planar Species [(tBu2PCH2SiMe2)2N]RuCl. J. Mol. Cat. A: Chemical, 2004, 224, 51.

Ozerov, O.; Watson, L. A.; Pink, M.; Baik, M-H.; Caulton, K. G. Terminal Acetylenes React to Increase Unsaturation in [(tBu2PCH2SiMe2)2N]Re(H)4. Organometallics, 2004, 23, 4934.

Walstrom, A. N.; Watson, L. A.; Pink, M.; Caulton, K. G.  Facile Insertion of Terminal Acetylenes in the RuII-NR2 Bond of a 14-valence Electron Complex. Organometallics, 2004, 23, 4814.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. Transformation of acyclic alkenes to hydrido carbynes by (PNPR)Re complexes. J. Am. Chem. Soc., 2004, 126, 6363.

Ozerov, O.; Pink, M.; Watson, L. A.; Caulton, K. G. Aromatic vs. Aliphatic C-H Cleavage of Alkyl-Substituted Pyridines By (PNPiPr)Re Compounds. J. Am. Chem. Soc., 2004, 126, 2105.

Watson, L. A.; Franzman, B.; Bollinger, J. C.; Caulton, K. G. p-Donor Olefin Substituents alter Olefin Binding to CpFe(CO)2+.  New J. Chem., 2003, 27, 1769.

Basuli, F.; Watson, L. A.; Huffman, J. C.; Mindiola, D. J. Phosphaazaallene and phosphinylimide complexes stemming from a terminal and four-coordinate titanium phosphinidene. J. Chem. Soc., Dalton Trans., 2003, 22, 4228.

Ozerov, O.; Watson, L. A.; Pink, M.; Caulton, K. G. A p-Basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand. J. Am. Chem. Soc., 2003, 125, 9604.

Ho, V. M.; Watson, L. A.; Caulton, K. G. Double C(sp3) Dehydrogenation as a Route to Coordinated Arduengo Carbenes: Experiment and Computation on Comparative π-Acidity.  New J. Chem., 2003, 27, 1446.

Watson, L. A.; Ozerov, O.; Pink, M.; Caulton, K. G. Four-coordinate, Planar Ru(II).  A Triplet State as a Response to a 14 Valence Electron Configuration.  J. Am. Chem. Soc., 2003, 125, 8426.

Ozerov, O. V.; Huffman, J. C.; Watson, L. A.; Caulton, K. G. Conversion of Ethylene to Hydride and Ethylidyne by Amido Rhenium Polyhydride. Organometallics, 2003, 22, 2539.

Watson, L. A.; Coalter, J. N.; Ozerov, O.; Pink, M.; Huffman, J. C.; Caulton, K. G. Amido/Phosphine Pincer Hydrides of Ruthenium. New J. Chem., 2003, 27, 263.

Ozerov, O. V.; Gerard, H. F.; Watson, L. A.; Huffman, J. C.; Caulton, K. G. Double Silyl Migration Converting ORe[NSiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] Substructures.  Inorg. Chem., 2002, 41, 5615.

Watson, L. A.; Eisenstein, O. Entropy Explained: the origin of some simple trends.  J. Chem. Ed., 2002, 79, 1269.

Watson, L. A.; Caulton, K. G.  Assessing Isomeric Structures of Pincer-ligated Ruthenium and Osmium Polyhydrides using Density Functional Calculations.  Molecular Physics, 2002, 100, 385.

Watson, L. A.; Yandulov, D. V.; Caulton, K. G. C-Do (Do=π-donor, F) Cleavage in H2C:CH(Do) by (Cp2ZrHCl)n: Mechanism, Agostic Fluorines, and a Carbene of Zr(IV).  J. Am. Chem. Soc., 2001, 123, 603.

   

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